Issue 22, 2013
From the journal:

Chemical Communications

Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers†

Poh Wai Chia,‡a   Davide Bello,‡a   Alexandra M. Z. Slawina  and  David O'Hagan*a  

* Corresponding authors

a University of St Andrews, School of Chemistry and Centre for Biomolecular Sciences, North Haugh, St Andrews, Fife, UK
E-mail: do1@st-andrews.ac.uk
Fax: +44 (0)1334 463800
Tel: +44 (0)1334 467171

Abstract

The reaction of acetylene ethers with difluorocarbene (CF2), generated from the Ruppert–Prakash reagent, unexpectedly gave rise to co-produced fluorinated bicyclic [2.1.1]-hex-2-ene and cyclohepta-1,4-diene ring products.

Graphical abstract: Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

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Article information

DOI
https://doi.org/10.1039/C3CC39066G
Article type
Communication
Submitted
19 Dec 2012
Accepted
25 Jan 2013
First published
28 Jan 2013

Chem. Commun., 2013,49, 2189-2191

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Fluorinated 5- and 7-membered carbacycle motifs by reaction of difluorocarbene with acetylene ethers

P. W. Chia, D. Bello, A. M. Z. Slawin and D. O'Hagan, Chem. Commun., 2013, 49, 2189 DOI: 10.1039/C3CC39066G

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