Issue 23, 2013
From the journal:

Chemical Communications

A new class of highly solvatochromic dicyano rhenate(i) diimine complexes – synthesis, photophysics and photocatalysis†

Larry Tso-Lun Lo,a   Sze-Wing Lai,a   Shek-Man Yiua  and  Chi-Chiu Ko*a  

* Corresponding authors

a Department of Biology and Chemistry, City University of Hong Kong, Tat Chee Avenue, Kowloon, Hong Kong, China
E-mail: vinccko@cityu.edu.hk
Fax: +852-3442-0522
Tel: +852-3442-6958

Abstract

A new class of dicarbonyl dicyano rhenate(I) diimine complexes, cis,trans-[Re(CO)2(CN)2(N–N)]−, with highly environmentally sensitive MLCT absorption and emission properties was synthesised and characterised. Preliminary experiments revealed that these complexes are active photocatalysts for CO2 reduction.

Graphical abstract: A new class of highly solvatochromic dicyano rhenate(i) diimine complexes – synthesis, photophysics and photocatalysis

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Article information

DOI
https://doi.org/10.1039/C3CC39189B
Article type
Communication
Submitted
24 Dec 2012
Accepted
01 Feb 2013
First published
01 Feb 2013

Chem. Commun., 2013,49, 2311-2313

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A new class of highly solvatochromic dicyano rhenate(I) diimine complexes – synthesis, photophysics and photocatalysis

L. Tso-Lun Lo, S. Lai, S. Yiu and C. Ko, Chem. Commun., 2013, 49, 2311 DOI: 10.1039/C3CC39189B

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