Issue 26, 2013
From the journal:

Chemical Communications

Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions†

Dong Liu,ab   Jian-Ping Lang*a  and  Brendan F. Abrahamsc  

* Corresponding authors

a College of Chemistry, Chemical Engineering and Materials Science, Soochow University, 199 RenAi Road, Suzhou 215123, Jiangsu, P. R. China
E-mail: jplang@suda.edu.cn
Fax: +86 512 65880089
Tel: +86 512 65882865

b College of Chemistry and Materials Science, Huaibei Normal University, Huaibei 235000, P. R. China

c School of Chemistry, University of Melbourne, Victoria 3010, Australia

Abstract

The SCSC transformation of a 1D polymer [Cd(1,3-bdc)(4-spy)2]n produced a 2D polymer [Cd(1,3-bdc)(4-spy)(HT-ppcb)0.5]n through the [2+2] photodimerization reaction. Hydrothermal reactions of HT-ppcb with CdCl2, 1,3-H2bdc and H2O2 afforded another 2D polymer {[Cd(H2O)(1,3-bdc)(bpbpf)]·H2O}n in which HT-ppcb underwent in situ oxidation to form a unique furan-based ligand bpbpf.

Graphical abstract: Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions

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Article information

DOI
https://doi.org/10.1039/C3CC39286D
Article type
Communication
Submitted
30 Dec 2012
Accepted
12 Feb 2013
First published
14 Feb 2013

Chem. Commun., 2013,49, 2682-2684

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Stepwise ligand transformations through [2+2] photodimerization and hydrothermal in situ oxidation reactions

D. Liu, J. Lang and B. F. Abrahams, Chem. Commun., 2013, 49, 2682 DOI: 10.1039/C3CC39286D

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