Issue 41, 2013

[RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources

Abstract

[RuIV(F20-TPP)Cl2][H2(F20-TPP) = meso-tetrakis(pentafluorophenyl)porphyrin] is an active catalyst for both inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons in good to high product yields using phosphoryl azides as nitrene sources.

Graphical abstract: [RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources

Supplementary files

Article information

Article type
Communication
Submitted
09 Feb 2013
Accepted
28 Mar 2013
First published
03 Apr 2013

Chem. Commun., 2013,49, 4619-4621

[RuIV(F20-TPP)Cl2] efficiently catalysed inter- and intra-molecular nitrene insertion into sp3 C–H bonds of hydrocarbons using phosphoryl azides as nitrene sources

W. Xiao, J. Wei, C. Zhou and C. Che, Chem. Commun., 2013, 49, 4619 DOI: 10.1039/C3CC41110A

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