Issue 32, 2013
From the journal:

Chemical Communications

Simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and methoxycarbonylation of vinyl arenes†

Tina M. Konrad,a   Jamie T. Durrani,a   Christopher J. Cobleyb  and  Matthew L. Clarke*a  

* Corresponding authors

a School of Chemistry, University of St Andrews, EaStCHEM, St Andrews, Fife, UK
E-mail: mc28@st-andrews.ac.uk
Fax: +44 (0)1334 463808
Tel: +44 (0)1334 463850

b Chirotech Technology Ltd. Dr Reddys Laboratories (EU) Limited, 410 Cambridge Science Park, Milton road, Cambridge, UK

Abstract

Using a family of novel mononuclear and dinuclear palladium complexes of phanephos ligands, the simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and alkoxycarbonylation of styrene derivatives has been realised for the first time.

Graphical abstract: Simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and methoxycarbonylation of vinyl arenes

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Article information

DOI
https://doi.org/10.1039/C3CC41291A
Article type
Communication
Submitted
19 Feb 2013
Accepted
04 Mar 2013
First published
05 Mar 2013
This article is Open Access

Chem. Commun., 2013,49, 3306-3308

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Simultaneous control of regioselectivity and enantioselectivity in the hydroxycarbonylation and methoxycarbonylation of vinyl arenes

T. M. Konrad, J. T. Durrani, C. J. Cobley and M. L. Clarke, Chem. Commun., 2013, 49, 3306 DOI: 10.1039/C3CC41291A

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