A rare example of a porous Ca-MOF for the controlled release of biologically active NO

Stuart R. Miller; Elsa Alvarez; Lucie Fradcourt; Thomas Devic; Stefan Wuttke; Paul S. Wheatley; Nathalie Steunou; Christian Bonhomme; Christel Gervais; Danielle Laurencin; Russell E. Morris; Alexandre Vimont; Marco Daturi; Patricia Horcajada; Christian Serre

doi:10.1039/C3CC41987H

A rare example of a porous Ca-MOF for the controlled release of biologically active NO†

Stuart R. Miller,‡^a Elsa Alvarez,‡^a Lucie Fradcourt,^a Thomas Devic,*^a Stefan Wuttke,^ab Paul S. Wheatley,^c Nathalie Steunou,^a Christian Bonhomme,^d Christel Gervais,^d Danielle Laurencin,^e Russell E. Morris,^c Alexandre Vimont,^b Marco Daturi,^b Patricia Horcajada*^a and Christian Serre*^a

Author affiliations

* Corresponding authors

^a Institut Lavoisier, UMR CNRS 8180, Université de Versailles Saint-Quentin-en-Yvelines, 45 avenue des Etats-Unis, 78035 Versailles cedex, France
E-mail: devic@chimie.uvsq.fr, horcajada@chimie.uvsq.fr, serre@chimie.uvsq.fr
Fax: +33 139254452
Tel: +33 139254371

^b Laboratoire Catalyse et Spectrochimie, ENSICAEN, Université de Caen, CNRS, 6 Bd Maréchal Juin, 14050 Caen, France

^c EaStChem School of Chemistry, University of St Andrews, Purdie Building, St Andrews KY16 9ST, UK

^d Laboratoire de Chimie de la Matière Condensée de Paris, Université Pierre et Marie Curie Paris 06 UMR CNRS 7574, Collège de France, 11 Place Marcelin Berthelot, 75231 Paris Cedex 05, France

^e Institut Charles Gerhardt de Montpellier, UMR 5253, CNRS UM2 UM1 ENSCM, CC 1701 Université de Montpellier 2, Place E. Bataillon, 34095 Montpellier cedex 5, France

Abstract

A 1D-microporous 3D calcium tetracarboxylate MOF has been solvothermally prepared and its structure solved from single crystal data. It exhibits coordinatively unsaturated Ca²⁺ Lewis acid sites able to trap and deliver nitric oxide at a biological level.

Chemical Communications

A rare example of a porous Ca-MOF for the controlled release of biologically active NO†

Abstract

Supplementary files

Article information

Download Citation

Permissions

A rare example of a porous Ca-MOF for the controlled release of biologically active NO

Social activity

Search articles by author

Spotlight

Advertisements