Issue 54, 2013
From the journal:

Chemical Communications

Ruthenium-catalyzed aerobic oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes: a new route to isoquinolones†

Mallu Chenna Reddy,a   Rajendran Manikandana  and  Masilamani Jeganmohan*a  

* Corresponding authors

a Department of Chemistry, Indian Institute of Science Education and Research, Pune 411021, India
E-mail: mjeganmohan@iiserpune.ac.in

Abstract

The oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes in the presence of a catalytic amount of [{RuCl2(p-cymene)}2], Cu(OAc)2·H2O and KPF6 in acetic acid under air gave isoquinolones in good to excellent yields.

Graphical abstract: Ruthenium-catalyzed aerobic oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes: a new route to isoquinolones

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Article information

DOI
https://doi.org/10.1039/C3CC42683A
Article type
Communication
Submitted
12 Apr 2013
Accepted
16 May 2013
First published
16 May 2013

Chem. Commun., 2013,49, 6060-6062

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Ruthenium-catalyzed aerobic oxidative cyclization of aromatic and heteroaromatic nitriles with alkynes: a new route to isoquinolones

M. C. Reddy, R. Manikandan and M. Jeganmohan, Chem. Commun., 2013, 49, 6060 DOI: 10.1039/C3CC42683A

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