Issue 53, 2013
From the journal:

Chemical Communications

Enantioselective self-assembly of antiferromagnetic hexacopper(ii) wheels with chiral amino acid oxamates†

Thais Grancha,a   Jesús Ferrando-Soria,‡a   Joan Cano,a   Francesc Lloret,a   Miguel Julve,a   Giovanni De Munno,*b   Donatella Armentanob  and  Emilio Pardo*a  

* Corresponding authors

a Departament de Química Inorgánica, Instituto de Ciencia Molecular (ICMOL), Universitat de Valéncia, 46980 Paterna, Valéncia, Spain
E-mail: Emilio.Pardo@uv.es
Fax: +34 3543273
Tel: +34 3544442

b Dipartimento di Chimica e Tecnologie Chimiche, Universitá della Calabria, Cosenza, Italy
E-mail: demunno@unical.it

Abstract

The Cu2+-mediated self-assembly of oxamato-based ligands derived from either the (S)- or (R)-enantiomers of the amino acid valine leads to the formation of two antiferromagnetically coupled homochiral anionic hexacopper(II) wheels in the presence of templating tetramethylammonium countercations.

Graphical abstract: Enantioselective self-assembly of antiferromagnetic hexacopper(ii) wheels with chiral amino acid oxamates

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Article information

DOI
https://doi.org/10.1039/C3CC42776E
Article type
Communication
Submitted
15 Apr 2013
Accepted
14 May 2013
First published
14 May 2013

Chem. Commun., 2013,49, 5942-5944

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Enantioselective self-assembly of antiferromagnetic hexacopper(II) wheels with chiral amino acid oxamates

T. Grancha, J. Ferrando-Soria, J. Cano, F. Lloret, M. Julve, G. De Munno, D. Armentano and E. Pardo, Chem. Commun., 2013, 49, 5942 DOI: 10.1039/C3CC42776E

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