A microporous metal–organic open framework containing uncoordinated carbonyl groups as postsynthetic modification sites for cation exchange and Tb3+ sensing

Jianwei Cao; Yanfei Gao; Yanqin Wang; Chunfang Du; Zhiliang Liu

doi:10.1039/C3CC43168A

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A microporous metal–organic open framework containing uncoordinated carbonyl groups as postsynthetic modification sites for cation exchange and Tb³⁺ sensing†

Jianwei Cao,‡^a Yanfei Gao,‡^a Yanqin Wang,^a Chunfang Du^a and Zhiliang Liu*^a

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* Corresponding authors

^a College of Chemistry and Chemical Engineering, Key Laboratory of Nanomagnetic and Functional Materials, Inner Mongolia University, Hohhot, P. R. China
E-mail: cezlliu@imu.edu.cn
Fax: +86-471-4992147
Tel: +86-471-4995414

Abstract

A novel 3D microporous compound [Zn₃(Httca)₂(4,4′-bpy)(H₂O)₂]_n (MOF–COOH) containing uncoordinated carbonyl groups pointing to the pores was prepared. The uncoordinated carbonyl groups in the channels can act as postsynthetic modification sites for cation exchange. The MOF–COOH compound can effectively and selectively serve as an antenna for sensitizing the visible-emitting Tb³⁺ cation.

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Article information

DOI: https://doi.org/10.1039/C3CC43168A
Article type: Communication
Submitted: 29 Apr 2013
Accepted: 11 Jun 2013
First published: 12 Jun 2013

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Chem. Commun., 2013,49, 6897-6899

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A microporous metal–organic open framework containing uncoordinated carbonyl groups as postsynthetic modification sites for cation exchange and Tb³⁺ sensing

J. Cao, Y. Gao, Y. Wang, C. Du and Z. Liu, Chem. Commun., 2013, 49, 6897 DOI: 10.1039/C3CC43168A

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Chemical Communications