A new iterative bridge formation strategy has been employed in the synthesis of a series of [n](2,11)teropyrenophanes (n = 7–9). The generation of the nonplanar teropyrene system, which is calculated to be bent through 178.7° for the smallest homologue (n = 7), is accomplished using a VID reaction of a cyclophanemonoene precursor for the first time.
teropyrenophanes (n = 7–9): a series of armchair SWCNT segments](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C3CC43268H&imageInfo.ImageIdentifier.Year=2013)
B. L. Merner, K. S. Unikela, L. N. Dawe, D. W. Thompson and G. J. Bodwell, Chem. Commun., 2013, 49, 5930 DOI: 10.1039/C3CC43268H
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