Issue 73, 2013
From the journal:

Chemical Communications

Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex†

Thorsten Höke,a   Eberhardt Herdtwecka  and  Thorsten Bach*a  

* Corresponding authors

a Department Chemie and Catalysis Research Center (CRC), Technische Universität München, 85747 Garching, Germany
E-mail: thorsten.bach@ch.tum.de
Fax: +49 89 28913315
Tel: +49 89 28913330

Abstract

Enantioselective (up to 74% ee) and regioselective C–H amination reactions of 3-benzylquinolones were achieved with a chiral C2-symmetric Rh(II) complex exhibiting two lactam binding sites for substrate coordination via hydrogen bonds.

Graphical abstract: Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(ii) complex

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Article information

DOI
https://doi.org/10.1039/C3CC44197K
Article type
Communication
Submitted
04 Jun 2013
Accepted
09 Jul 2013
First published
05 Aug 2013

Chem. Commun., 2013,49, 8009-8011

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Hydrogen-bond mediated regio- and enantioselectivity in a C–H amination reaction catalysed by a supramolecular Rh(II) complex

T. Höke, E. Herdtweck and T. Bach, Chem. Commun., 2013, 49, 8009 DOI: 10.1039/C3CC44197K

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