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Abstract | Cited by

The reaction site of the Co(II) porphyrin created by an amide group and coordinating 1,2-dimethylimidazole at the fifth site activated an O2 molecule, and then hydroxylated the meso-carbon of the ligand. The biomimic O2 activation under mild conditions is described.

Graphical abstract: Biomimic O2 activation hydroxylates a meso-carbon of the porphyrin ring regioselectively under mild conditions

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