Issue 73, 2013
From the journal:

Chemical Communications

Hexagonal molecular “palladawheel”†

Qi-Qiang Wang,a   Victor W. Daya  and  Kristin Bowman-James*a  

* Corresponding authors

a Department of Chemistry, University of Kansas, Lawrence, Kansas 66045, USA
E-mail: kbjames@ku.edu

Abstract

A hexagonal molecular “palladawheel” consisting of six N,N’-diphenyl-2,6-pyridinedicarboxamide–Pd(II) pincer complexes held together via six Pd⋯O[double bond, length as m-dash]CAmide bonds was efficiently synthesized and crystallographically characterized. The hexameric ring possesses C3 (pseudo-S6) symmetry with up-down alternating phenyl substituents acting as interior “spokes” and exterior “propellers.”

Graphical abstract: Hexagonal molecular “palladawheel”

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Article information

DOI
https://doi.org/10.1039/C3CC44714F
Article type
Communication
Submitted
23 Jun 2013
Accepted
21 Jul 2013
First published
22 Jul 2013

Chem. Commun., 2013,49, 8042-8044

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Hexagonal molecular “palladawheel”

Q. Wang, V. W. Day and K. Bowman-James, Chem. Commun., 2013, 49, 8042 DOI: 10.1039/C3CC44714F

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