Issue 78, 2013
From the journal:

Chemical Communications

Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group†

Luo-Qiang Zhang,a   Shiping Yang,a   Xiaolei Huang,a   Jingsong Youa  and  Feijie Song*a  

* Corresponding authors

a Key Laboratory of Green Chemistry and Technology of Ministry of Education, College of Chemistry, and State Key Laboratory of Biotherapy, West China Medical School, Sichuan University, 29 Wangjiang Road, Chengdu 610064, PR China
E-mail: fsong@scu.edu.cn
Fax: +86-28-85412285

Abstract

A highly efficient and selective Ru-catalyzed direct C2-olefination of indoles, pyrroles, and carbazoles assisted by a removable N-dimethylcarbamoyl group has been developed by using O2 as the terminal oxidant. Both electron-deficient and unactivated alkenes are applicable to the protocol.

Graphical abstract: Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

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Article information

DOI
https://doi.org/10.1039/C3CC44787A
Article type
Communication
Submitted
26 Jun 2013
Accepted
30 Jul 2013
First published
31 Jul 2013

Chem. Commun., 2013,49, 8830-8832

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Aerobic Ru-catalyzed direct C2-olefination of N-heteroarenes with alkenes directed by a removable N-dimethylcarbamoyl group

L. Zhang, S. Yang, X. Huang, J. You and F. Song, Chem. Commun., 2013, 49, 8830 DOI: 10.1039/C3CC44787A

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