Issue 95, 2013
From the journal:

Chemical Communications

Enantioselective Pd(ii)–Pd(iv) catalysis utilizing a SPRIX ligand: efficient construction of chiral 3-oxy-tetrahydrofurans†

Kazuhiro Takenaka,a   Yogesh D. Dhagea  and  Hiroaki Sasai*a  

* Corresponding authors

a The Institute of Scientific and Industrial Research (ISIR), Osaka University, Mihogaoka, Ibaraki-shi, Osaka 567-0047, Japan
E-mail: sasai@sanken.osaka-u.ac.jp
Fax: +81-6-6879-8469
Tel: +81-6-6879-8465

Abstract

Novel enantioselective catalysis involving a Pd(II)–Pd(IV) cycle was developed by utilizing a SPRIX ligand. Treatment of alkenyl alcohols with a catalytic amount of Pd–SPRIX and TfOH in the presence of PhI(OAc)2 gave optically active 3-oxy-tetrahydrofuran derivatives in good yields.

Graphical abstract: Enantioselective Pd(ii)–Pd(iv) catalysis utilizing a SPRIX ligand: efficient construction of chiral 3-oxy-tetrahydrofurans

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Article information

DOI
https://doi.org/10.1039/C3CC44797A
Article type
Communication
Submitted
26 Jun 2013
Accepted
09 Oct 2013
First published
14 Oct 2013

Chem. Commun., 2013,49, 11224-11226

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Enantioselective Pd(II)–Pd(IV) catalysis utilizing a SPRIX ligand: efficient construction of chiral 3-oxy-tetrahydrofurans

K. Takenaka, Y. D. Dhage and H. Sasai, Chem. Commun., 2013, 49, 11224 DOI: 10.1039/C3CC44797A

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