Transmetalation is the rate-limiting step. [R–Pd–Ar] was suggested to be the resting species from the kinetic studies. Quantitative measurement of the transmetalation of ArZnCl with [R–Pd–Ar] from a live Pd-catalysed oxidative coupling reaction was conducted and the corresponding activation enthalpy was determined as 12.3 kcal mol−1.
J. Li, L. Jin, C. Liu and A. Lei, Chem. Commun., 2013, 49, 9615 DOI: 10.1039/C3CC44894K
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