A 3D microporous covalent organic framework with exceedingly high C3H8/CH4 and C2 hydrocarbon/CH4 selectivity

Heping Ma; Hao Ren; Shuang Meng; Zhuojun Yan; Huanyu Zhao; Fuxing Sun; Guangshan Zhu

doi:10.1039/C3CC45217D

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A 3D microporous covalent organic framework with exceedingly high C₃H₈/CH₄ and C₂ hydrocarbon/CH₄ selectivity†

Heping Ma,^a Hao Ren,*^a Shuang Meng,^a Zhuojun Yan,^a Huanyu Zhao,^a Fuxing Sun^a and Guangshan Zhu*^a

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* Corresponding authors

^a State Key Laboratory of Inorganic Synthesis & Preparative Chemistry, Jilin University, Changchun, China
E-mail: zhugs@jlu.edu.cn
Fax: +86 431-8516-8331

Abstract

Here we present a new 3D microporous COF with a uniform pore size (0.64 nm). MCOF-1 exhibits high adsorption selectivity towards C₃H₈, C₂H₆ and C₂H₄ over CH₄ owing to the pore size and preferential adsorption.

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Article information

DOI: https://doi.org/10.1039/C3CC45217D
Article type: Communication
Submitted: 11 Jul 2013
Accepted: 22 Aug 2013
First published: 23 Aug 2013

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Chem. Commun., 2013,49, 9773-9775

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A 3D microporous covalent organic framework with exceedingly high C₃H₈/CH₄ and C₂ hydrocarbon/CH₄ selectivity

H. Ma, H. Ren, S. Meng, Z. Yan, H. Zhao, F. Sun and G. Zhu, Chem. Commun., 2013, 49, 9773 DOI: 10.1039/C3CC45217D

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Chemical Communications