Formation of an unprecedented (CuBr)5 cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect

Antony Lapprand; Antoine Bonnot; Michael Knorr; Youann Rousselin; Marek M. Kubicki; Daniel Fortin; Pierre D. Harvey

doi:10.1039/C3CC45284K

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Formation of an unprecedented (CuBr)₅ cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect†

Antony Lapprand,^ab Antoine Bonnot,^a Michael Knorr,*^b Youann Rousselin,^c Marek M. Kubicki,*^c Daniel Fortin^a and Pierre D. Harvey*^a

Author affiliations

* Corresponding authors

^a Département de Chimie, Université de Sherbrooke, Sherbrooke, Québec, Canada J1K 2R1
E-mail: Pierre.Harvey@USherbrooke.ca

^b Institut UTINAM UMR CNRS 6213, Université de Franche-Comté, 25030 Besançon, France
E-mail: michael.knorr@univ-fcomte.fr

^c Institut de Chimie Moléculaire UMR CNRS 5260, Université de Bourgogne, F-21078 Dijon, France
E-mail: marek.kubicki@u-bourgogne.fr

Abstract

A unique pentanuclear cluster within a zeolite-type polymer ([Cu₅(μ₄-Br)(μ₃-Br)₂(μ₂-Br)₂](μ₂-MeSPr)₃)_n (1; void space >81%) and a luminescent 1D ([Cu(μ₃-I)]₄(MeSPr)₃)_n polymer, 2, are formed when MeSPr reacts with CuBr and CuI.

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Article information

DOI: https://doi.org/10.1039/C3CC45284K
Article type: Communication
Submitted: 12 Jul 2013
Accepted: 01 Aug 2013
First published: 01 Aug 2013

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Chem. Commun., 2013,49, 8848-8850

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Formation of an unprecedented (CuBr)₅ cluster and a zeolite-type 2D-coordination polymer: a surprising halide effect

A. Lapprand, A. Bonnot, M. Knorr, Y. Rousselin, M. M. Kubicki, D. Fortin and P. D. Harvey, Chem. Commun., 2013, 49, 8848 DOI: 10.1039/C3CC45284K

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