Issue 82, 2013
From the journal:

Chemical Communications

A three-dimensional π-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units†

Guo Fan Jin,a   Jo-Hyun Hwang,b   Jong-Dae Lee,*b   Kyung-Ryang Wee,a   Il-Hwan Suha  and  Sang Ook Kang*a  

* Corresponding authors

a Department of Advanced Materials Chemistry, Korea University, Sejong-ro 2511, Sejong city 339-700, South Korea
E-mail: sangok@korea.ac.kr
Fax: +82-44-860-1331
Tel: +82-44-860-1334

b Department of Chemistry, Chosun University, 309 Pilmun-daero, Dong-gu, Gwangju 501-759, South Korea
E-mail: jdlee@chosun.ac.kr
Fax: +82-62-230-6645
Tel: +82-62-230-6645

Abstract

Electron accepting capability is greatly improved for B-phenylated tri-phenyl-o-carborane (1) through a favorable electronic interaction between the two adjoining phenyl-π* and cage carbon-σ* orbitals.

Graphical abstract: A three-dimensional π-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units

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Article information

DOI
https://doi.org/10.1039/C3CC45313H
Article type
Communication
Submitted
14 Jul 2013
Accepted
13 Aug 2013
First published
13 Aug 2013

Chem. Commun., 2013,49, 9398-9400

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A three-dimensional π-electron acceptor, tri-phenyl-o-carborane, bearing a rigid conformation with end-on phenyl units

G. F. Jin, J. Hwang, J. Lee, K. Wee, I. Suh and S. O. Kang, Chem. Commun., 2013, 49, 9398 DOI: 10.1039/C3CC45313H

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