Issue 82, 2013
From the journal:

Chemical Communications

Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙†

Hans Peter Reisenauer,*a   Jarosław Romański,b   Grzegorz Mlostoń*b  and  Peter R. Schreinera  

* Corresponding authors

a Institute of Organic Chemistry, Justus-Liebig University, Heinrich-Buff-Ring 58, D-35392 Giessen, Germany
E-mail: reisenauer@org.chemie.uni-giessen.de
Fax: +49-641-9934309
Tel: +49-641-9934380

b Department of Organic and Applied Chemistry, University of Lodz, Tamka 12, 91-493 Lodz, Poland
E-mail: gmloston@uni.lodz.pl
Fax: +48 42 6655162
Tel: +48 42 6355761

Abstract

The atmospherically highly relevant methylsulfinyl radical CH3(O)S˙ was generated thermally under flash pyrolysis conditions and isolated in Ar matrices at 10 K; the allyl radical is a byproduct. CH3(O)S˙ and its D3- and 13C-isotopologues were characterized through the excellent agreement between experimental and computed IR and UV/Vis spectra.

Graphical abstract: Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙

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Article information

DOI
https://doi.org/10.1039/C3CC45379K
Article type
Communication
Submitted
16 Jul 2013
Accepted
14 Aug 2013
First published
15 Aug 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 9467-9469

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Matrix isolation and spectroscopic properties of the methylsulfinyl radical CH3(O)S˙

H. P. Reisenauer, J. Romański, G. Mlostoń and P. R. Schreiner, Chem. Commun., 2013, 49, 9467 DOI: 10.1039/C3CC45379K

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