Issue 80, 2013
From the journal:

Chemical Communications

Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers†

Haeri Lee,a   Tae Hwan Noha  and  Ok-Sang Jung*a  

* Corresponding authors

a Department of Chemistry, Pusan National University, Pusan 609-735, Korea
E-mail: oksjung@pusan.ac.kr
Fax: +82 51 516 7421
Tel: +82 51 510 2591

Abstract

Self-assembly of CuX2 (X− = ClO4− and BF4−) with 2,3-bis(nicotinoyloxy)naphthalene yields a 1D loop-chain skeleton. The loop-chains form an ensemble constituting a unique 3D kagome-type structure with both hexagonal and trigonal supra-channels. The unprecedented supra-channel effects on the catalytic oxidation of 3,5-di-tert-butylcatechol to 3,5-di-tert-butylbenzoquinone were investigated.

Graphical abstract: Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers

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Article information

DOI
https://doi.org/10.1039/C3CC45587D
Article type
Communication
Submitted
23 Jul 2013
Accepted
08 Aug 2013
First published
08 Aug 2013

Chem. Commun., 2013,49, 9182-9184

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Reversible supra-channel effects: 3D kagome structure and catalysis via a molecular array of 1D coordination polymers

H. Lee, T. H. Noh and O. Jung, Chem. Commun., 2013, 49, 9182 DOI: 10.1039/C3CC45587D

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