Issue 84, 2013
From the journal:

Chemical Communications

A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage†

De-Liang Long,*a   Jun Yan,a   Andreu Ruiz de la Oliva,a   Christoph Busche,a   Haralampos N. Miras,a   R. John Erringtonb  and  Leroy Cronin*a  

* Corresponding authors

a WestCHEM, School of Chemistry, The University of Glasgow, Glasgow, UK
E-mail: Deliang.Long@glasgow.ac.uk, Lee.Cronin@glasgow.ac.uk
Web: http://www.croninlab.com
Fax: +44 (0)141-330-4888
Tel: +44 (0)141-330-6650

b School of Chemistry, Newcastle University, Newcastle upon Tyne, UK

Abstract

The new tungstatoiodate, α-[H5W18O59(IO3)]6−, containing IVO3− within a {W18O54} metal oxide framework has been prepared and shown by X-ray crystallography and mass spectrometry to be derived from the fully oxidised [H3W18O56(IO6)]6− by two-electron reduction accompanied by a redox-triggered structural rearrangement where three I–O covalent bonds are broken.

Graphical abstract: A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

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Article information

DOI
https://doi.org/10.1039/C3CC45659E
Article type
Communication
Submitted
25 Jul 2013
Accepted
30 Aug 2013
First published
02 Sep 2013

Chem. Commun., 2013,49, 9731-9733

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A redox-triggered structural rearrangement in an iodate-templated polyoxotungstate cluster cage

D. Long, J. Yan, A. Ruiz de la Oliva, C. Busche, H. N. Miras, R. J. Errington and L. Cronin, Chem. Commun., 2013, 49, 9731 DOI: 10.1039/C3CC45659E

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