Issue 79, 2013
From the journal:

Chemical Communications

Phosphoramidate synthesis via copper-catalysed aerobic oxidative coupling of amines and H-phosphonates†

Jamie Fraser,a   Laura J. Wilson,a   Rebecca K. Blundella  and  Christopher J. Hayes*a  

* Corresponding authors

a School of Chemistry, University of Nottingham, University Park, Nottingham, UK
E-mail: chris.hayes@nottingham.ac.uk
Fax: +44 (0)115 951 3564
Tel: +44 (0)115 951 3045

Abstract

The copper-catalysed oxidative coupling of amines and H-phosphonates to produce phosphoramidates has been achieved using CuI as the catalyst and O2 (present in air) as the sole oxidant.

Graphical abstract: Phosphoramidate synthesis via copper-catalysed aerobic oxidative coupling of amines and H-phosphonates

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Article information

DOI
https://doi.org/10.1039/C3CC45680C
Article type
Communication
Submitted
25 Jul 2013
Accepted
15 Aug 2013
First published
15 Aug 2013

Chem. Commun., 2013,49, 8919-8921

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Phosphoramidate synthesis via copper-catalysed aerobic oxidative coupling of amines and H-phosphonates

J. Fraser, L. J. Wilson, R. K. Blundell and C. J. Hayes, Chem. Commun., 2013, 49, 8919 DOI: 10.1039/C3CC45680C

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