Issue 86, 2013
From the journal:

Chemical Communications

A robust amino-functionalized titanium(iv) based MOF for improved separation of acid gases†

Sébastien Vaesen,a   Vincent Guillerm,b   Qingyuan Yang,cg   Andrew D. Wiersum,d   Bartosz Marszalek,e   Barbara Gil,e   Alexandre Vimont,f   Marco Daturi,f   Thomas Devic,b   Philip L. Llewellyn,d   Christian Serre,*b   Guillaume Maurin*c  and  Guy De Weireld*a  

* Corresponding authors

a Service de Thermodynamique, Faculté Polytechnique, Université de Mons, 20 Place du Parc, Mons, Belgium
E-mail: guy.deweireld@umons.ac.be

b Institut Lavoisier, UMR CNRS 8180–Université de Versailles St Quentin en Yvelines, 45 avenue des Etats-Unis, Versailles, France
E-mail: serre@chimie.uvsq.fr

c Institut Charles Gerhardt Montpellier, UMR CNRS 5253, UM2, ENSCM, UM1, Place E. Bataillon, Montpellier cedex 05, 34095 France
E-mail: gmaurin@univ-montp2.fr

d MADIREL, UMR CNRS 7246 – Aix-Marseille Univ. Centre de Saint-Jérôme, Marseille cedex 20, France

e Department of Chemistry, Jagiellonian University in Krakow, Ingardena 3, Krakow 30-060, Poland

f Laboratoire Catalyse et Spectrochimie, ENSICAEN, Université de Caen Basse Normandie, CNRS, 6, Boulevard du Maréchal Juin, Caen, France

g State Key Laboratory of Organic–Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China

Abstract

A combination of adsorption, microcalorimetry, infra-red spectroscopy and modeling has been implemented to reveal the potential of the H2S resistant amino-functionalized Ti MOF MIL-125 porous solid for the concomitant elimination of CO2 and H2S from biogas and natural gas.

Graphical abstract: A robust amino-functionalized titanium(iv) based MOF for improved separation of acid gases

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Article information

DOI
https://doi.org/10.1039/C3CC45828H
Article type
Communication
Submitted
04 Aug 2013
Accepted
06 Sep 2013
First published
06 Sep 2013

Chem. Commun., 2013,49, 10082-10084

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A robust amino-functionalized titanium(IV) based MOF for improved separation of acid gases

S. Vaesen, V. Guillerm, Q. Yang, A. D. Wiersum, B. Marszalek, B. Gil, A. Vimont, M. Daturi, T. Devic, P. L. Llewellyn, C. Serre, G. Maurin and G. De Weireld, Chem. Commun., 2013, 49, 10082 DOI: 10.1039/C3CC45828H

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