Unprecedented activation and CO2 capture properties of an elastic single-molecule trap

Mario Wriedt; Julian P. Sculley; Wolfgang M. Verdegaal; Andrey A. Yakovenko; Hong-Cai Zhou

doi:10.1039/C3CC45866K

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Unprecedented activation and CO₂ capture properties of an elastic single-molecule trap†

Mario Wriedt,*^a Julian P. Sculley,^b Wolfgang M. Verdegaal,^b Andrey A. Yakovenko^b and Hong-Cai Zhou^b

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* Corresponding authors

^a Department of Chemistry & Biomolecular Science, Clarkson University, Potsdam, NY, USA
E-mail: mwriedt@clarkson.edu

^b Department of Chemistry, Texas A&M University, College Station, TX, USA
E-mail: zhou@chem.tamu.edu

Abstract

The activation and CO₂ capture properties of a microporous metal–organic framework with elastic single-molecule traps were systematically investigated. This material shows a unique low-energy gas-purge activation capability, high CO₂ adsorption selectivities over various gases and optimized working capacities per energy of 2.9 mmol kJ⁻¹ at 128 °C.

This article is part of the themed collection: CO2 Separation, Capture and Reuse

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Article information

DOI: https://doi.org/10.1039/C3CC45866K
Article type: Communication
Submitted: 31 Jul 2013
Accepted: 23 Aug 2013
First published: 23 Aug 2013

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Chem. Commun., 2013,49, 9612-9614

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Unprecedented activation and CO₂ capture properties of an elastic single-molecule trap

M. Wriedt, J. P. Sculley, W. M. Verdegaal, A. A. Yakovenko and H. Zhou, Chem. Commun., 2013, 49, 9612 DOI: 10.1039/C3CC45866K

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Chemical Communications