Issue 91, 2013
From the journal:

Chemical Communications

Preparation of allylboronates by Pd-catalysed borylative cyclisation of dienynes†

Ruth López-Durán,a   Alicia Martos-Redruejo,a   Elena Buñuel,a   Virtudes Pardo-Rodrígueza  and  Diego J. Cárdenas*a  

* Corresponding authors

a Departamento de Química Orgánica, Facultad de Ciencias, Universidad Autónoma de Madrid, Campus de Cantoblanco, 28049-Madrid, Spain
E-mail: diego.cardenas@uam.es
Fax: +34 914973966
Tel: +34 914974358

Abstract

Reaction of a variety of dienynes with bis(pinacolato)diboron catalysed by Pd bis(trifluoroacetate) affords allylic boronates containing five or six membered carbo- or heterocycles, by concomitant formation of one C–C and one C–B bonds. Resulting allylboronates can be employed for a variety of subsequent transformations.

Graphical abstract: Preparation of allylboronates by Pd-catalysed borylative cyclisation of dienynes

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Article information

DOI
https://doi.org/10.1039/C3CC45879B
Article type
Communication
Submitted
01 Aug 2013
Accepted
23 Sep 2013
First published
26 Sep 2013

Chem. Commun., 2013,49, 10691-10693

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Preparation of allylboronates by Pd-catalysed borylative cyclisation of dienynes

R. López-Durán, A. Martos-Redruejo, E. Buñuel, V. Pardo-Rodríguez and D. J. Cárdenas, Chem. Commun., 2013, 49, 10691 DOI: 10.1039/C3CC45879B

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