Reaction of a variety of dienynes with bis(pinacolato)diboron catalysed by Pd bis(trifluoroacetate) affords allylic boronates containing five or six membered carbo- or heterocycles, by concomitant formation of one C–C and one C–B bonds. Resulting allylboronates can be employed for a variety of subsequent transformations.
R. López-Durán, A. Martos-Redruejo, E. Buñuel, V. Pardo-Rodríguez and D. J. Cárdenas, Chem. Commun., 2013, 49, 10691 DOI: 10.1039/C3CC45879B
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