Issue 85, 2013
From the journal:

Chemical Communications

Asymmetric ring-opening of oxabenzonorbornadiene with amines promoted by a chiral iridium-monophosphine catalyst†

Renshi Luo,*ab   Jianhua Liao,b   Ling Xie,b   Wenjun Tang*a  and  Albert S. C. Chanc  

* Corresponding authors

a State Key Laboratory of Bioorganic and Natural Products Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, 345 Ling Ling Road, Shanghai, China

b School of Pharmaceutical Sciences, Gannan Medical University, 1 Yixueyuan Road, Jiangxi, Ganzhou, China
E-mail: luorenshi2010@163.com
Tel: +86-0797-8169775

c Institute of Creativity, Hong Kong Baptist University, Hong Kong, China

Abstract

A new iridium-monophosphine catalyst is found to be efficient for asymmetric ring-opening of benzonorbornadiene with amines, providing a series of chiral substituted dihydronaphthalenes in high yields (up to 98%) and excellent enantioselectivities (>99%).

Graphical abstract: Asymmetric ring-opening of oxabenzonorbornadiene with amines promoted by a chiral iridium-monophosphine catalyst

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Article information

DOI
https://doi.org/10.1039/C3CC46009F
Article type
Communication
Submitted
09 Aug 2013
Accepted
02 Sep 2013
First published
02 Sep 2013

Chem. Commun., 2013,49, 9959-9961

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Asymmetric ring-opening of oxabenzonorbornadiene with amines promoted by a chiral iridium-monophosphine catalyst

R. Luo, J. Liao, L. Xie, W. Tang and A. S. C. Chan, Chem. Commun., 2013, 49, 9959 DOI: 10.1039/C3CC46009F

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