Issue 83, 2013
From the journal:

Chemical Communications

Water-controlled synthesis and single-crystal structural transformations of a cyanide-bridged W(iv)–Ni(ii) molecular wheel complex and 3D networks†

Dao-Peng Zhang,abc   Li-Fang Zhang,a   Guo-Ling Lia  and  Zhong-Hai Ni*a  

* Corresponding authors

a School of Chemical Engineering and Technology, China University of Mining and Technology, XuZhou 221116, P. R. China
E-mail: nizhonghaicumt@gmail.com

b College of Chemical Engineering, Shandong University of Technology, Zibo 255049, P. R. China

c Department of Chemistry, University of Science and Technology Beijing, Beijing 100083, P. R. China

Abstract

One cyanide-bridged W(IV)–Ni(II) wheel-like complex and two three-dimensional (3D) networks can be directly synthesized based on K4[W(CN)8] and [Ni(L)](ClO4)2 precursors by controlling the quantity of water in organic solvent. The water-controlled single-crystal structural transformations among these complexes are described.

Graphical abstract: Water-controlled synthesis and single-crystal structural transformations of a cyanide-bridged W(iv)–Ni(ii) molecular wheel complex and 3D networks

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C3CC46063K
Article type
Communication
Submitted
08 Aug 2013
Accepted
16 Aug 2013
First published
19 Aug 2013

Chem. Commun., 2013,49, 9582-9584

Permissions

Request permissions

Water-controlled synthesis and single-crystal structural transformations of a cyanide-bridged W(IV)–Ni(II) molecular wheel complex and 3D networks

D. Zhang, L. Zhang, G. Li and Z. Ni, Chem. Commun., 2013, 49, 9582 DOI: 10.1039/C3CC46063K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements