Issue 86, 2013
From the journal:

Chemical Communications

2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents†

Hikaru Yanai,*a   Yoichi Takahashi,a   Haruhiko Fukaya,a   Yasuo Dobashia  and  Takashi Matsumotoa  

* Corresponding authors

a School of Pharmacy, Tokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan
E-mail: yanai@toyaku.ac.jp

Abstract

Stable and easy-to-handle zwitterions containing carbanion and pyridinium moieties were synthesized, and their structural studies by both X-ray crystallography and theoretical methods revealed the stereoelectronic effect in the zwitterionic ‘C−–C–N+’ system.

Graphical abstract: 2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents

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Article information

DOI
https://doi.org/10.1039/C3CC46171H
Article type
Communication
Submitted
12 Aug 2013
Accepted
03 Sep 2013
First published
05 Sep 2013

Chem. Commun., 2013,49, 10091-10093

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2-(Pyridinium-1-yl)-1,1-bis(triflyl)ethanides: structural behaviour and availability as bis(triflyl)ethylating reagents

H. Yanai, Y. Takahashi, H. Fukaya, Y. Dobashi and T. Matsumoto, Chem. Commun., 2013, 49, 10091 DOI: 10.1039/C3CC46171H

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