Issue 90, 2013
From the journal:

Chemical Communications

A tetranuclear Cu4(μ3-OH)2-based metal–organic framework (MOF) with sulfonate–carboxylate ligands for proton conduction†

Xi-Yan Dong,ab   Rui Wang,a   Jia-Bin Li,a   Shuang-Quan Zang,*a   Hong-Wei Houa  and  Thomas C. W. Makac  

* Corresponding authors

a College of Chemistry and Molecular Engineering, Zhengzhou University, Zhengzhou 450001, China
E-mail: zangsqzg@zzu.edu.cn
Fax: +86 371 6778 0136
Tel: +86 371 6778 0136

b School of Physics and Chemistry, Henan Polytechnic University, Jiaozuo 454000, China

c Department of Chemistry and Center of Novel Functional Molecules, The Chinese University of Hong Kong, Shatin, New Territories, Hong Kong SAR, China

Abstract

A new tetranuclear Cu4(μ3-OH)2-based metal–organic framework (MOF) with sulfonate–carboxylate ligands features large hydrophilic channels. This MOF exhibits proton conductivity over 10−3 S cm−1 at 85–100 °C and 98% relative humidity and colossal dielectric constant.

Graphical abstract: A tetranuclear Cu4(μ3-OH)2-based metal–organic framework (MOF) with sulfonate–carboxylate ligands for proton conduction

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Article information

DOI
https://doi.org/10.1039/C3CC46226A
Article type
Communication
Submitted
14 Aug 2013
Accepted
23 Sep 2013
First published
04 Oct 2013

Chem. Commun., 2013,49, 10590-10592

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A tetranuclear Cu4(μ3-OH)2-based metal–organic framework (MOF) with sulfonate–carboxylate ligands for proton conduction

X. Dong, R. Wang, J. Li, S. Zang, H. Hou and T. C. W. Mak, Chem. Commun., 2013, 49, 10590 DOI: 10.1039/C3CC46226A

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