Orientational variation, solvate composition and molecular flexibility in well-ordered cocrystals of the fullerene C70 with bis(ethylenedithio)tetrathiafulvalene

Kamran B. Ghiassi; Marilyn M. Olmstead; Alan L. Balch

doi:10.1039/C3CC46367B

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Orientational variation, solvate composition and molecular flexibility in well-ordered cocrystals of the fullerene C₇₀ with bis(ethylenedithio)tetrathiafulvalene†

Kamran B. Ghiassi,^a Marilyn M. Olmstead^a and Alan L. Balch*^a

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* Corresponding authors

^a Department of Chemistry, University of California, One Shields Avenue, Davis, CA, USA
E-mail: mmolmstead@ucdavis.edu, albalch@ucdavis.edu
Fax: +1 530 752 2820
Tel: +1 530 752 0941

Abstract

Cocrystallization of C₇₀ with bis(ethylenedithio)tetrathiafulvalene (ET) produces two different solvates, C₇₀·ET·C₆H₆ and 2C₇₀·2ET·CS₂, which show distinctly different overlap between the fullerene and ET molecules.

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Article information

DOI: https://doi.org/10.1039/C3CC46367B
Article type: Communication
Submitted: 20 Aug 2013
Accepted: 02 Oct 2013
First published: 04 Oct 2013

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Chem. Commun., 2013,49, 10721-10723

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Orientational variation, solvate composition and molecular flexibility in well-ordered cocrystals of the fullerene C₇₀ with bis(ethylenedithio)tetrathiafulvalene

K. B. Ghiassi, M. M. Olmstead and A. L. Balch, Chem. Commun., 2013, 49, 10721 DOI: 10.1039/C3CC46367B

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