Issue 99, 2013

Transposition of chirality from diphosphonate metal–organic framework precursors onto porous lanthanide pyrophosphates

Abstract

Chiral porous inorganic materials, lanthanide pyrophosphates, were prepared from chiral porous metal–organic framework precursors, which upon thermal decomposition transpose their chirality and porosity onto the inorganic framework. It is argued that this synthesis concept may be extended to other chiral porous inorganic solids.

Graphical abstract: Transposition of chirality from diphosphonate metal–organic framework precursors onto porous lanthanide pyrophosphates

Supplementary files

Article information

Article type
Communication
Submitted
26 Aug 2013
Accepted
21 Oct 2013
First published
22 Oct 2013

Chem. Commun., 2013,49, 11668-11670

Transposition of chirality from diphosphonate metal–organic framework precursors onto porous lanthanide pyrophosphates

F. Shi, F. A. Almeida Paz, P. Ribeiro-Claro and J. Rocha, Chem. Commun., 2013, 49, 11668 DOI: 10.1039/C3CC46503A

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