A straightforward, reduction-free method for the synthesis of organometallic cobalamins has been developed. Stable phenylacetylide derivatives were characterized by X-ray analysis, showing a pronounced influence of the electronic nature of substituents on their structure.
M. Chromiński, A. Lewalska and D. Gryko, Chem. Commun., 2013, 49, 11406 DOI: 10.1039/C3CC47210H
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