Issue 97, 2013
From the journal:

Chemical Communications

Hydrosilylation kinetics of silicon nanocrystals†

Wei Sun,a   Chenxi Qian,a   Melanie L. Mastronardi,a   Muan Weib  and  Geoffrey A. Ozin*a  

* Corresponding authors

a Department of Chemistry, University of Toronto, 80 St. George Street, Toronto, Ontario, Canada
E-mail: gozin@chem.utoronto.ca

b Department of Materials Science and Engineering, University of Toronto, 184 College Street, Toronto, Ontario, Canada

Abstract

Hydrosilylation kinetics of hydride-capped silicon nanocrystals with 1-decene are reported for the first time. In a side-by-side comparison, it is found that microwave heating has no evident acceleration effect on the hydrosilylation rate relative to conventional thermal heating.

Graphical abstract: Hydrosilylation kinetics of silicon nanocrystals

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Article information

DOI
https://doi.org/10.1039/C3CC47212D
Article type
Communication
Submitted
20 Sep 2013
Accepted
15 Oct 2013
First published
15 Oct 2013

Chem. Commun., 2013,49, 11361-11363

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Hydrosilylation kinetics of silicon nanocrystals

W. Sun, C. Qian, M. L. Mastronardi, M. Wei and G. A. Ozin, Chem. Commun., 2013, 49, 11361 DOI: 10.1039/C3CC47212D

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