Issue 100, 2013
From the journal:

Chemical Communications

Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates†

David M. Cousins,a   Matthew G. Davidson*a  and  Daniel García-Vivó*a  

* Corresponding authors

a Centre for Sustainable Chemical Technologies, Department of Chemistry, University of Bath, Claverton Down, Bath, UK
E-mail: m.g.davidson@bath.ac.uk, garciavdaniel@uniovi.es

Abstract

Metalation of an ammonium tris(phenol) ligand affords new lithium/sodium derivatives having central pseudocubane motifs in which one of the metallic positions is replaced by a four-coordinate hydrogen atom.

Graphical abstract: Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates

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Article information

DOI
https://doi.org/10.1039/C3CC47393G
Article type
Communication
Submitted
27 Sep 2013
Accepted
23 Oct 2013
First published
24 Oct 2013
This article is Open Access
Creative Commons BY license

Chem. Commun., 2013,49, 11809-11811

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Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates

D. M. Cousins, M. G. Davidson and D. García-Vivó, Chem. Commun., 2013, 49, 11809 DOI: 10.1039/C3CC47393G

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