Solvent dependence of crystal morphology, donor/anion ratio and electrical conductivity in a series of hexagonal supramolecular organic conductors based on diiodo(pyrazino)tetrathiafulvalene (DIP)

Tatsuro Imakubo; Ryosuke Murayama

doi:10.1039/C2CE26739J

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Solvent dependence of crystal morphology, donor/anion ratio and electrical conductivity in a series of hexagonal supramolecular organic conductors based on diiodo(pyrazino)tetrathiafulvalene (DIP)†

Tatsuro Imakubo*^a and Ryosuke Murayama^a

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* Corresponding authors

^a Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188, Japan
E-mail: imakubo@nagaokaut.ac.jp
Fax: +81-258-47-9325
Tel: +81-258-47-9325

Abstract

A series of hexagonal supramolecular organic conductors has been tailored by the iodine bond based on the selenium-free π-donor and halogen-free solvent. The solvent dependence of crystal morphology, donor/anion ratio and electrical conductivity was investigated together with characteristic recyclability of the neutral donor molecule.

This article is part of the themed collection: Halogen bonding: from self-assembly to materials and biomolecules

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DOI: https://doi.org/10.1039/C2CE26739J
Article type: Communication
Submitted: 23 Oct 2012
Accepted: 29 Nov 2012
First published: 20 Dec 2012

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CrystEngComm, 2013,15, 3072-3075

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Solvent dependence of crystal morphology, donor/anion ratio and electrical conductivity in a series of hexagonal supramolecular organic conductors based on diiodo(pyrazino)tetrathiafulvalene (DIP)

T. Imakubo and R. Murayama, CrystEngComm, 2013, 15, 3072 DOI: 10.1039/C2CE26739J

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CrystEngComm

Solvent dependence of crystal morphology, donor/anion ratio and electrical conductivity in a series of hexagonal supramolecular organic conductors based on diiodo(pyrazino)tetrathiafulvalene (DIP)†

Abstract

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Solvent dependence of crystal morphology, donor/anion ratio and electrical conductivity in a series of hexagonal supramolecular organic conductors based on diiodo(pyrazino)tetrathiafulvalene (DIP)

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