Issue 2, 2013
From the journal:

Dalton Transactions

Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands†

Martín Hernández-Juárez,a   Mónica Vaquero,b   Eleuterio Álvarez,b   Verónica Salazar*a  and  Andrés Suárez*b  

* Corresponding authors

a Centro de Investigaciones Químicas, Universidad Autónoma del Estado de Hidalgo, Carretera Pachuca-Tulancingo Km 4.5, 42184, Mineral de la Reforma, Hidalgo, Mexico
E-mail: salazar@uaeh.edu.mx
Fax: +52 771 717200x6502
Tel: +52 771 1550933

b Instituto de Investigaciones Químicas (IIQ), Consejo Superior de Investigaciones Científicas and Universidad de Sevilla, Avda Américo Vespucio No. 49, 41092, Sevilla, Spain
E-mail: andres.suarez@iiq.csic.es
Fax: +34954460565
Tel: +34 954489556

Abstract

The preparation of new Ru(II) complexes incorporating fac-coordinated lutidine-derived CNC ligands is reported. These derivatives are selectively deprotonated by tBuOK at one of the methylene arms of the pincer, leading to catalytically active species in the hydrogenation of imines.

Graphical abstract: Hydrogenation of imines catalysed by ruthenium(ii) complexes based on lutidine-derived CNC pincer ligands

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Article information

DOI
https://doi.org/10.1039/C2DT31907A
Article type
Communication
Submitted
20 Aug 2012
Accepted
26 Sep 2012
First published
03 Oct 2012

Dalton Trans., 2013,42, 351-354

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Hydrogenation of imines catalysed by ruthenium(II) complexes based on lutidine-derived CNC pincer ligands

M. Hernández-Juárez, M. Vaquero, E. Álvarez, V. Salazar and A. Suárez, Dalton Trans., 2013, 42, 351 DOI: 10.1039/C2DT31907A

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