Issue 4, 2013

A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides

Abstract

A general, atom-economical method for the synthesis of phosphaalkenes is reported via the net coupling of primary alkyl or aryl phosphines with aryl or alkyl isocyanides at zirconium. The phosphorus-containing ligand can be liberated as the phosphaformamide from zirconium by reaction with an organic electrophile.

Graphical abstract: A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides

Supplementary files

Article information

Article type
Paper
Submitted
02 Oct 2012
Accepted
18 Oct 2012
First published
22 Oct 2012

Dalton Trans., 2013,42, 1159-1167

A general synthesis of phosphaalkenes at zirconium with liberation of phosphaformamides

A. J. Roering, L. T. Elrod, J. K. Pagano, S. L. Guillot, S. M. Chan, J. M. Tanski and R. Waterman, Dalton Trans., 2013, 42, 1159 DOI: 10.1039/C2DT32322B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements