Issue 6, 2013
From the journal:

Dalton Transactions

Synthesis and characterization of tantalum silsesquioxane complexes†

Pascal Guillo,ab   Meg E. Fasulo,a   Michael I. Lipschutza  and  T. Don Tilley*ab  

* Corresponding authors

a Department of Chemistry, University of California, Berkeley, CA 94720-1461, USA
E-mail: tdtilley@berkeley.edu

b Chemical Sciences Division, Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, CA 94720, USA

Abstract

Tantalum polyhedral oligosilsesquioxane (POSS) complexes have been synthesised and characterized. X-ray structures of these complexes revealed that the coordination number of the tantalum center greatly affects the cube-like silsesquioxane framework.

Graphical abstract: Synthesis and characterization of tantalum silsesquioxane complexes

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Article information

DOI
https://doi.org/10.1039/C2DT32601A
Article type
Communication
Submitted
31 Oct 2012
Accepted
11 Dec 2012
First published
13 Dec 2012

Dalton Trans., 2013,42, 1991-1995

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Synthesis and characterization of tantalum silsesquioxane complexes

P. Guillo, M. E. Fasulo, M. I. Lipschutz and T. D. Tilley, Dalton Trans., 2013, 42, 1991 DOI: 10.1039/C2DT32601A

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