Issue 18, 2013
From the journal:

Dalton Transactions

Insights into the mechanism for gold catalysis: behaviour of gold(i) amide complexes in solution†

Mariusz Bobin,a   Iain J. Day,a   Stephen M. Roea  and  Eddy M. E. Viseux*a  

* Corresponding authors

a School of Life Sciences, Department of Chemistry, University of Sussex, Brighton, UK
E-mail: e.m.e.viseux@sussex.ac.uk
Tel: +44 (0) 1273 678621

Abstract

We report the synthesis and activity of new mononuclear and dinuclear gold amide complexes 1–7. The dinuclear complexes 6b and 7 were characterised by single crystal X-ray analysis. We also report solution NMR and freezing point depression experiments to rationalise their behaviour in solution and question the de-ligation process invoked in gold catalysis.

Graphical abstract: Insights into the mechanism for gold catalysis: behaviour of gold(i) amide complexes in solution

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DOI
https://doi.org/10.1039/C3DT33039G
Article type
Paper
Submitted
19 Dec 2012
Accepted
25 Feb 2013
First published
11 Mar 2013

Dalton Trans., 2013,42, 6592-6602

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Insights into the mechanism for gold catalysis: behaviour of gold(I) amide complexes in solution

M. Bobin, I. J. Day, S. M. Roe and E. M. E. Viseux, Dalton Trans., 2013, 42, 6592 DOI: 10.1039/C3DT33039G

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