Issue 26, 2013
From the journal:

Dalton Transactions

High symmetry superoctahedron cluster [MnIII18O14]26+ from the use of N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine†

Ai-Ju Zhou,*a   Ji-Dong Leng,b   Jin-Sheng Hua  and  Ming-Liang Tong*b  

* Corresponding authors

a Guangzhou Key Laboratory for Environmentally Functional Materials and Technology, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China
E-mail: ahcfzhouaiju@163.com
Fax: +86 3936 6908
Tel: +86 3936 6908

b Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, State Key Laboratory of Optoelectronic Materials and Technologies, School of Chemistry and Chemical Engineering, Sun Yat-Sen University, Guangzhou 510275, China
E-mail: Tongml@sysu.edu.cn
Fax: +86 8411 2275
Tel: +86 8411 0966

Abstract

The use of flexible N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine has provided one new high symmetry superoctahedron with unprecedented aesthetically-pleasing MnIII18 clusters, which exhibits out-of-phase signals indicative of the slow magnetic relaxation.

Graphical abstract: High symmetry superoctahedron cluster [MnIII18O14]26+ from the use of N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine

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Article information

DOI
https://doi.org/10.1039/C3DT50695A
Article type
Communication
Submitted
13 Mar 2013
Accepted
16 Apr 2013
First published
17 Apr 2013

Dalton Trans., 2013,42, 9428-9431

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High symmetry superoctahedron cluster [MnIII18O14]26+ from the use of N,N,N′,N′-tetrakis(2-hydroxyethyl)ethylenediamine

A. Zhou, J. Leng, J. Hu and M. Tong, Dalton Trans., 2013, 42, 9428 DOI: 10.1039/C3DT50695A

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