Issue 45, 2013
From the journal:

Dalton Transactions

Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets†

Masaki Nishio,a   Natsuko Motokawa,b   Miho Takemurab  and  Hitoshi Miyasaka*c  

* Corresponding authors

a Department of Chemistry, Division of Material Sciences, Graduate School of Natural Science and Technology, Kanazawa University, Kakuma-machi, Kanazawa 920-1192, Japan

b Department of Chemistry, Graduate School of Science, Tohoku University, 6-3 Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan

c Institute for Materials Research, Tohoku University, 2-1-1 Katahira, Aoba-ku, Sendai 920-8577, Japan
E-mail: miyasaka@imr.tohoku.ac.jp
Fax: +81-22-215-2031
Tel: +81-22-215-2030

Abstract

Pyrene-intercalated layered compounds, [{Ru2(O2CCF3)4}2(TCNQRx)]·2(pyrene) (TCNQRx = 7,7,8,8-tetracyano-p-quinodimethane derivatives; Rx = H4 and F4), were synthesized. Pyrene prohibits intralayer electron transfer of [Ru2II,II] → TCNQRx, even in the compound with Rx = F4, from occurring.

Graphical abstract: Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets

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Article information

DOI
https://doi.org/10.1039/C3DT51271A
Article type
Communication
Submitted
16 May 2013
Accepted
10 Jul 2013
First published
11 Jul 2013

Dalton Trans., 2013,42, 15898-15901

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Modification of charge transfer in a two-dimensional donor/acceptor framework by the insertion of another donor-type molecule into electronegative interlayer pockets

M. Nishio, N. Motokawa, M. Takemura and H. Miyasaka, Dalton Trans., 2013, 42, 15898 DOI: 10.1039/C3DT51271A

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