Issue 45, 2013

Bottom-up assembly of ultrathin sub-micron size metal–organic framework sheets

Abstract

A solution-based two-dimensional interfacial reaction between 5,10,15,20-tetra(4-pyridyl)-porphinato zinc(II) (ZnTPyP, 1) and Cu(NO3)2·3H2O, 2, results in the assembly of uniform preferentially oriented highly crystalline metal–organic framework nanosheets, NAFS-21 that have sub-micron planar size and mono-molecular thickness.

Graphical abstract: Bottom-up assembly of ultrathin sub-micron size metal–organic framework sheets

Supplementary files

Article information

Article type
Communication
Submitted
26 Jun 2013
Accepted
28 Aug 2013
First published
03 Sep 2013
This article is Open Access
Creative Commons BY-NC license

Dalton Trans., 2013,42, 15931-15936

Bottom-up assembly of ultrathin sub-micron size metal–organic framework sheets

R. Makiura and O. Konovalov, Dalton Trans., 2013, 42, 15931 DOI: 10.1039/C3DT51703A

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