Issue 47, 2013

First example of a hexadentate bicyclic phthalocyanine analogue containing a divalent metal center

Abstract

A reaction of 1,2-dicyanobenzene and lithium methoxide at 70 °C in methanol yielded the half-phthalocyanine intermediate, which coordinates to a cadmium(II) ion in the subsequent reaction step to give the first example of a six-coordinate phthalocyanine analogue containing a divalent metal ion at the center.

Graphical abstract: First example of a hexadentate bicyclic phthalocyanine analogue containing a divalent metal center

Supplementary files

Article information

Article type
Communication
Submitted
08 Aug 2013
Accepted
30 Sep 2013
First published
01 Oct 2013

Dalton Trans., 2013,42, 16486-16489

First example of a hexadentate bicyclic phthalocyanine analogue containing a divalent metal center

T. Fukuda, N. Shigeyoshi, A. Fuyuhiro and N. Ishikawa, Dalton Trans., 2013, 42, 16486 DOI: 10.1039/C3DT52170B

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