Issue 7, 2013
From the journal:

New Journal of Chemistry

Denitrogen alkene polymerization of bisdiazo compounds by copper(ii) catalysts†

Longqiang Xiao,a   Yan Li,a   Liqiong Liaoa  and  Lijian Liu*a  

* Corresponding authors

a College of Chemistry and Molecular Sciences, Wuhan University, Wuhan, China
E-mail: liulj@whu.edu.cn
Tel: +86 27 68756825

Abstract

Bisdiazo compounds were synthesized and underwent denitrogen alkene polymerization (DNAP) via the formation of an sp2 carbon bond in the presence of copper(II) catalysts, affording unsaturated polymers with molecular weights in the range of 2900 to 35 400 Da. The copper-catalyzed denitrogen alkene polymerization of bisdiazo compounds allows the efficient synthesis of unsaturated polyesters.

Graphical abstract: Denitrogen alkene polymerization of bisdiazo compounds by copper(ii) catalysts

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Article information

DOI
https://doi.org/10.1039/C3NJ00339F
Article type
Letter
Submitted
01 Apr 2013
Accepted
16 Apr 2013
First published
17 Apr 2013

New J. Chem., 2013,37, 1874-1877

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Denitrogen alkene polymerization of bisdiazo compounds by copper(II) catalysts

L. Xiao, Y. Li, L. Liao and L. Liu, New J. Chem., 2013, 37, 1874 DOI: 10.1039/C3NJ00339F

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