Issue 1, 2013
From the journal:

Organic & Biomolecular Chemistry

N-Heterocyclic carbene catalyzed synthesis of oxime esters†

Dieter Enders,*a   André Grossmanna  and  David Van Craena  

* Corresponding authors

a Institute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
E-mail: enders@rwth-aachen.de
Fax: (+49) 241-809-2127

Abstract

A triazolium salt derived N-heterocyclic carbene catalyzes the redox esterification reaction between α–β-unsaturated aldehydes and oximes. The resulting saturated oxime esters were obtained in very good yields for a broad range of aliphatic, aromatic and heteroaromatic substrates.

Graphical abstract: N-Heterocyclic carbene catalyzed synthesis of oxime esters

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Article information

DOI
https://doi.org/10.1039/C2OB26974K
Article type
Paper
Submitted
18 Sep 2012
Accepted
15 Oct 2012
First published
16 Oct 2012

Org. Biomol. Chem., 2013,11, 138-141

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N-Heterocyclic carbene catalyzed synthesis of oxime esters

D. Enders, A. Grossmann and D. Van Craen, Org. Biomol. Chem., 2013, 11, 138 DOI: 10.1039/C2OB26974K

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