Issue 21, 2013
From the journal:

Organic & Biomolecular Chemistry

Elucidating absolute configuration of unsaturated alcoholsvia enantioselective acylation reactions†

Christina M. LeGay,a   Colton G. Boudreaua  and  Darren J. Derksen*a  

* Corresponding authors

a Department of Chemistry, St. Francis Xavier University, Physical Sciences Complex, 5009 Chapel Square, Antigonish, NS B2G 2W5, Canada
E-mail: dderksen@stfx.ca
Fax: +1-902-867-2414
Tel: +1-902-867-3918

Abstract

Enantioselective nucleophilic acylation catalysis provides a simple method of determining absolute configuration for unsaturated alcohols. Extension of this technique to natural products and synthetic compounds, as well as current limitations of this approach, are also described.

Graphical abstract: Elucidating absolute configuration of unsaturated alcohols via enantioselective acylation reactions

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Article information

DOI
https://doi.org/10.1039/C3OB40709H
Article type
Communication
Submitted
09 Apr 2013
Accepted
10 Apr 2013
First published
19 Apr 2013
This article is Open Access
Creative Commons BY license

Org. Biomol. Chem., 2013,11, 3432-3435

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Elucidating absolute configuration of unsaturated alcohols via enantioselective acylation reactions

C. M. LeGay, C. G. Boudreau and D. J. Derksen, Org. Biomol. Chem., 2013, 11, 3432 DOI: 10.1039/C3OB40709H

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