Issue 6, 2013
From the journal:

RSC Advances

Palladium catalyzed direct ortho C–H acylation of 2-arylpyridines using toluene derivatives as acylation reagents†

Zhipeng Xu,a   Biao Xianga  and  Peipei Sun*ab  

* Corresponding authors

a Jiangsu Key Laboratory of Biofunctional Materials, College of Chemistry and Materials Science, Nanjing Normal University, Nanjing, P. R. China

b Key Laboratory of Organic Synthesis of Jiangsu Province, College of Chemistry, Chemical Engineering and Materials Science, Soochow University, Suzhou 215123, P. R. China
E-mail: sunpeipei@njnu.edu.cn
Fax: (+86) 25 8589 1767
Tel: (+86) 25 8589 1767

Abstract

A facile ortho-acylation of 2-arylpyridines by a Pd-catalyzed oxidative C–H activation was developed, in which no prefunctionalized toluene derivatives were used as acylation reagents in a tandem reaction to form 2-pyridyldiaryl ketones with moderate yields.

Graphical abstract: Palladium catalyzed direct ortho C–H acylation of 2-arylpyridines using toluene derivatives as acylation reagents

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Article information

DOI
https://doi.org/10.1039/C2RA22208F
Article type
Communication
Submitted
18 Sep 2012
Accepted
03 Dec 2012
First published
04 Dec 2012

RSC Adv., 2013,3, 1679-1682

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Palladium catalyzed direct ortho C–H acylation of 2-arylpyridines using toluene derivatives as acylation reagents

Z. Xu, B. Xiang and P. Sun, RSC Adv., 2013, 3, 1679 DOI: 10.1039/C2RA22208F

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