Issue 6, 2013
From the journal:

Chemical Science

Enantioselective intermolecular bromoesterification of allylic sulfonamides†

Wei Zhang,a   Na Liu,a   Casi M. Schienebeck,a   Xin Zhou,a   Izarin I. Izhar,a   Ilia A. Guzeib  and  Weiping Tang*ab  

* Corresponding authors

a School of Pharmacy, University of Wisconsin, Madison, WI, USA

b Department of Chemistry, University of Wisconsin, Madison, WI, USA
E-mail: wtang@pharmacy.wisc.edu

Abstract

Highly enantioselective intermolecular bromoesterification of alkenes was achieved for the first time. Both C–O and C–Br bonds were introduced enantioselectively in this olefin addition reaction. The sulfonamide NH directing group is important for both the reactivity and enantioselectivity.

Graphical abstract: Enantioselective intermolecular bromoesterification of allylic sulfonamides

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Article information

DOI
https://doi.org/10.1039/C3SC50446H
Article type
Edge Article
Submitted
15 Feb 2013
Accepted
29 Mar 2013
First published
08 Apr 2013

Chem. Sci., 2013,4, 2652-2656

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Enantioselective intermolecular bromoesterification of allylic sulfonamides

W. Zhang, N. Liu, C. M. Schienebeck, X. Zhou, I. I. Izhar, I. A. Guzei and W. Tang, Chem. Sci., 2013, 4, 2652 DOI: 10.1039/C3SC50446H

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