Issue 13, 2013
From the journal:

Journal of Materials Chemistry A

Nanoconfined ammonia borane in a flexible metal–organic framework Fe–MIL-53: clean hydrogen release with fast kinetics†

Gadipelli Srinivas,*ab   Will Travis,c   Jamie Ford,ab   Hui Wu,ad   Zheng-Xiao Guoc  and  Taner Yildirim*ab  

* Corresponding authors

a NIST Center for Neutron Research, National Institute of Standards and Technology, Gaithersburg, Maryland, USA
E-mail: taner@seas.upenn.edu, gsrinivasphys@gmail.com
Fax: +1 1301-921-9847
Tel: +1 1301-975-6228

b Department of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania, USA

c Department of Chemistry, University College London, 20 Gordon Street, London, UK

d Department of Materials Science and Engineering, University of Maryland, College Park, Maryland, USA

Abstract

We demonstrated the dehydrogenation behaviour of nanoconfined ammonia borane (AB) in Fe–MIL-53, a flexible metal–organic framework (MOF) by solid state thermolysis. We observed clean hydrogen release with fast kinetics at reduced temperatures.

Graphical abstract: Nanoconfined ammonia borane in a flexible metal–organic framework Fe–MIL-53: clean hydrogen release with fast kinetics

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Article information

DOI
https://doi.org/10.1039/C3TA00037K
Article type
Communication
Submitted
04 Jan 2013
Accepted
12 Feb 2013
First published
12 Feb 2013

J. Mater. Chem. A, 2013,1, 4167-4172

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Nanoconfined ammonia borane in a flexible metal–organic framework Fe–MIL-53: clean hydrogen release with fast kinetics

G. Srinivas, W. Travis, J. Ford, H. Wu, Z. Guo and T. Yildirim, J. Mater. Chem. A, 2013, 1, 4167 DOI: 10.1039/C3TA00037K

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